New Superconducting and Semiconducting Fe-B Compounds Predicted with anAb InitioEvolutionary Search

New superconducting and semiconducting Fe-B compounds predicted with an ab initio evolutionary search.

New candidate ground states at 1:4, 1:2, and 1:1 compositions are identified in the well-known Fe-B system via a combination of ab initio high-throughput and evolutionary searches. We show that the proposed oP12-FeB2 stabilizes by a break up of 2D boron layers into 1D chains while oP10-FeB4 stabilizes by a distortion of a 3D boron network. The uniqueness of these configurations gives rise to a ...

detection of volatile compounds of medicinal plants with some nano-sorbents using modified or new methodologies and investigation of antioxidant activity of their methanolic extracts

in this work, a novel and fast method for direct analysis of volatile compounds (davc) of medicinal plants has been developed by holding a filament from different parts of a plant in the gc injection port. the extraction and analysis of volatile components of a small amount of plant were carried out in one-step without any sample preparation. after optimization of temperature, extraction time a...

Novel superconducting semiconducting superlattices: dislocation-induced superconductivity?

Novel superconducting superlattices with transition temperature in the range 2.5-6.4 K consisting only of semiconducting materials are discovered. Among them there are multilayers, including a wide-gap semiconductor as one of the components. It is shown that superconductivity is connected with the interfaces between two semiconductors containing regular grids of the misfit dislocations. The pos...

Cation-anion vacancy complexes in semiconducting compounds

Catalytic oxidation of toluene over LaBO3 (B= Fe, Mn and Co) and LaCo0.7B′0.3O3 (B′= Fe and Mn) perovskite-type

In this paper, LaBO3 perovskite type catalyst formulations were prepared by sol-gel auto combustion method using citric acid as the fuel. Activity of catalysts was tested in catalytic oxidation of toluene as a model of volatile organic compounds. LaCoO3 perovskite formulation showed the highest activity among LaBO3 (Fe, Mn and Co) perovskite catalysts. So, LaCoO3 perovskite based catalyst was s...